Heh.
"Screw" - a threaded fastener that is accepted directly by one or more of the mating parts, with no secondary fastener. Wood screws and sheetmetal screws are obvious examples of this.
"Bolt" - a threaded fastener that is accepted by a secondary fastener (nut,) and not RPT not by any of the mating parts.
Put simply, "a bolt is a screw with a nut on it." Properly stated, the fasteners that hold the cylinder head down would be called "screws." As would the fasteners for the differential cover, oil sump, timing chain cover, camshaft timing gear, ...
A "bolt" would be an example of most suspension fasteners (the nut may be welded to a mating part, but it is not the mating part, the fasteners for brake backing plates, and the like.
Note that this has nothing to do with head style - and that, in engineering terms, threaded fasteners are generally called out as "screws" unless you know a nut is going onto it in the final application (which is why you'll see "socket head capscrew," "hex head capscrew," "flat head capscrew," "reduced hex head capscrew," "flange head capscrew," and the like.)
So now, when you see me refer to "cylinder head screws," you'll have some idea of what I'm really talking about and why (because I've been doing that for a while...) I'd still like to know where the phrase "gudgeon pin" came from - I like it...