I just did this about a month ago (AA SYE, Tom Woods shaft).
Before this I had never opened anything with fluid in it before but I have put on a lift kit, lots of body repair/replacement/suspension type work when I was younger and am reasonably handy with repair/replace type stuff but I wouldn't be comfortable opening an engine or setting up gears.
My suggestions:
1- the printed instructions they send with the AA/Tomwoods kit are absolutely FANTASTIC. Easily the best I've ever seen outside of contract manufacturing. This document will be your bible and contains all that you need. It's very detailed which makes it seem complex but just because every step is well documented.
2- I didn't bother to remove the transfer case, I have a 4.5" lift and I had enough room with the rear driveshaft removed to sit under the truck (slightly hunched over). Not the most comfortable but taking it all out looked like even more trouble. The biggest advantage of removing it would be to thoroughly clean and rebuild it and it would also be easier to apply the RTV gasket maker material. You decide which you'd rather do. (Side note: with all the CFC stuff out there now I might consider buying a junkyard transfer case and building it on a bench then remove/replace.)
3- In addition to the basic hand tools (plus LOCK ring pliers and a 12 pt, 10mm socket) you'll need an ~8 inch extension for your socket to go on the front output shaft, also a breaker bar would be helpful along with a torque wrench.
4- You might want to go ahead and buy a new chain and shift fork pads (or that front aluminum shift fork with the molded plastic glides) as well as a new o-ring for the speedo gear so that you can replace them while you have it open. Otherwise you'll have to order them and wait...which sucks big time with the truck disabled in pieces in your garage.I speak from experience here.
5- I forgot to put the oil pickup tube back in the first time I sealed the case...even got the tailcone fully installed....big time F*CK ME!?!?!! moment there......and cleaning fresh RTV off is MUCH worse than cleaning off the original rtv gasket. So don't do that. Lol.
I ended up opening my case twice due to forgetfulness but I was still pretty pleased with myself when I finished. It's not something I'd do for the fun of it but the hardest part is just all the bolts you have to undo and the general messiness of dealing with ATF fluid.
Aside from the lock-rings nothing is really difficult or needs any 'forcing' or special tools/skills.
It's also one of those things that once you start it, you're definitely "all in" since the truck is disabled. But I find this gives me the motivation needed to see it through to completion. ymmv.
-Keith