The threaded end is bigger than the middle on these bolts. See the pix he posted of a bolt before. Crap and rust builds up the sleeve and sometimes makes it hard to remove.
The spring also appears to be under some tension. Is the spring just hanging there with the axle attached? If so you may need to take some of the weight of the axle off the spring. Spring bolts will commonly turn OK until the bolt comes out of the frame side, then if the spring is under any tension, the bolt will go crooked and jam in the sleeve.
Air tools are almost a required the first time you do your springs. You can commonly get an air gun on there and with some pressure from behind with a wrench about the size of the bolt itself, walk that bolt right out of that sleeve, much the same process that Goodbourbon was describing, but with a lot more spinning action
When you put that sucker together again, liberally coat all bolts with anti-seize from the head to the end of the threads. Also coat the spring eyes.