Think about it. If the tank is full, there will be very little air in the tank, and even then the vapor pressure will be high and above the ignition point. How do you think they run an electric pump in the tank.
The pin welder does not penetrate the skin of the tank, especially when the other side is cooled by gas. A pin welder also does not normally cause any arcing. It simply heats up the junction of the pin and the metal until the pin melts and bonds to the tank.