Well, after installing the new HG, header, distributor cap/rotor, wires, radiator, the problem isn't gone but it doesn't seem as bad? Not making as much smoke for as long at startup. While it used to smoke out the entire driveway for 10 minutes, it's now making.... quite a bit of smoke for about 2-3 minutes and tapering off. I seem to have lost a bit of low range power but gained a bit in the middle (suspect the gain is from header and cap/rotor).
Compression test didn't change at all. Around 160psi across the board. Leakdown also still looks good.
The one thing that definitely changed, is that I don't make smoke when warm, when disconnecting the #6 spark or fuel injector connector. Just runs a bit rough but exhaust stays clean.
When I had the head off, the cylinders all looked pretty clean. A bit of carbon on 3 and 4. Left exposed to air overnight, most of it just peeled up and flaked off. The block/head deck had no obvious scratches.
I did notice that before I changed everything over, the main rad hose from the head would pressure right up once the thermostat opened up. After the change over, it did this for one heat/cooling cycle, but hasn't done it since. Pressure now stays low enough that i can pinch the two walls together with a finger and thumb. I don't know what's normal rad pressure in these as most of my Jeeps had the older pressure bottle system, and rad pressure was always pretty high.
Seems like I have more than one problem, but that all the problems result in white smoke from the exhaust?
Keep in mind, the smoke doesn't appear at all if the Cat is removed from the equation.