You kinda forgot to mention one small important detail...is the 700R4 you have a 2 wheel or 4 wheel drive application?
They came in either a 27 spline or 32 spline version, depending on how heavy the vehicle was that it came from. The S10's were 27. The 1/2, 3/4, and 1 ton trucks, Suburbans, and Blazers all used the 32 spline output.
The best setup is to get the 4wd transmission, regardless of vehicle size, and get the full size NP208-231-241-242-249 adaptor with the matching transfer case input shaft. If you do that you can keep your transfercase and simply change out the input shaft. It's really not that difficult.
The fullsize utilizes the same 6 bolt mounting pattern that Jeep used on all the 1980 and up applications, fullsize Jeep, CJ, XJ, YJ, ZJ, MJ, KJ, JK, etc. The Jeeps used either a 21 or 23 spline input on the transfercases.
The S10's used the odd 5 bolt mounting pattern. I would strongly avoid using the S10 setup if you can avoid it. The Jeep 'cases are much easier and usually cheaper to get ahold of.