The steel used in cranes is very different then what you going to build a roll cage out of. It's a high martensite steel that is super strong but also very brittle.
You don't want marensite anywhere near the steel you use for a cage. An no, round does not distribute forces any better. For torsion yes it does, which we are not really dealing with, and for buckling yes a round shape is better but thats in a pure compression loading, cages are hardly ever in pure compression. For point loads sqaure or rect is better. Tube tends to dent with point loads, and how the stress is spread is more a function of joint design.
It will work fine. Only of my old buddies built his entire cage from square on his crusier and it worked awesome. And it got laid over plenty.
For the joints I would just cut and fold over then weld. It's just mild steel right so you shouldn't have to worry about the welds cooling to quickly I don't think.
Build it, use you head, make sure your welds are good and you'll be fine.