If I was a gambling man, I would bet that 6 lb label on the cap was a factory printing (casting) error, just missing the 1 in front of the 6. As someone said below, the temerature sensor and the thermostat do not see the hottest spot in the cooling system, they see more of an average engine block coolant temperature, so one can probably count on the gauge temperature being 10 to 20 degrees less than the hottest spot in the coolant side of the block. So at 230 F (which is what I hear many reporting their gauges to read under heavy loads) it is conceivable they are closer 250 F at the hottest liquid coolant / metal engine surface interface point which is where you want to avoid gas forming (boiling).
I have a bottle of antifreeze next to me that shows a 50/50 mix (not just water) having a boiling point of 265 F with a 15 lb cap!
lawson is right below, (his numbers surprized me so I had to check them) Pure water does boil at 230 F at 6 lbs of gauge pressure. I was also surprised to see that does boil at 250 F at 15 lbs, so antifreeze only adds 15 F degrees of differential to the boiling point at a 50/50 % mix, while reducing the thermal transfer efficiency since antifreeze has a lower heat capacity and lower heat transfer coeficient than water. Hmm.
Of course many people use antifreeze to avoid freeze damaged plastic bottles:bawl:.
If the 6 lb cap on the closed system was ever used (and maybe it was) and was not just a typo error, perhaps the open systems which vent liquid back and forth need a higher pressure cap than the closed systems which only vent gas (when working properly), and thus can operate at a lower system pressure (?). Also the older jeeps (closed systems) were not the newer HO's and I think they ran a little cooler than the newer ones (?).
Here is link to a nice site with a complete table of water boiling points versus absolute pressures. Remember to add 14.7 psi for atmospheric pressure first to get gauge pressures. The absolute pressures are what is listed on the tables.
http://www.engineeringtoolbox.com/boiling-point-water-d_926.html
Also, unless I am mistaken, the lower atmospheric pressure at high altitudes like Denver makes higher pressure caps necessary there as it is the absolute pressure (cap pressure plus atmospheric pressure) that actually determines the boiling point. The pressure in Denver is only 12.2 psi (14.7 - 12.2 = 2.5 Psi drop). Mexico city is 11.1 psi (3.6 psi less than sea level). I sure as hell would not run a 6 lb cap in Denver or Mexico city!
http://www.kinequip.com/pressure_terminology.asp
I tried to find a 50/50 antifreeze mix pressure (cap) versus boiling point table, but could not find one.
If there ever was a 6 lb cap for the plastic bottles, perhaps 5-90 can find it listed in one of his older FSMs????? 5-90, are you there????
I just checked my 1987-88 FSM and it lists 12 to 15 lbs for the pressure cap.