By mentioning 'defroster' I assume you mean the rear defroster??? At any rate, it may be that the system is just loaded down, defrosters have always been a high amp draw on the system, and so is the fan. By running the rear defroster, having the fan on mid to high speed, and the wipers going, you are putting a nice load on the system. You may cure this malady by purchasing and installing an alternator with a higher amp rating.