I'll let the suspension gurus tackle the angle part of your question, but the purpose of mounting one shock ahead of the axle and one behind is to control wheel hop and axle wrap-up during acceleration and braking.
I experienced this first-hand some years ago. I owned a 1968 AMC Javelin that was a late 1968 build. If any of you even remember the Javelin, you know that '68 was the first year. Mine was a 343 "Go Package" V-8 4-speed, and it really scooted. And it handled acceleration fairly well.
Fast forward a couple of years. I was getting into autocrossing more seriously and I wanted a vehicle I could flog on Sunday without worrying about getting to work on Monday. I was in a Javelin/AMX club, so brand was a no-brainer. I picked up another 343 Javelin 4-speed.
First time out I couldn't believe it was the same brand of vehicle. I was running my competition tires, but I couldn't keep the rear tires hooked up. During the following week I started digging, and found that my "new" acquisition was a very early build. My original Javelin had staggered shocks -- the "new" one did not. Fortunately, the upper mounting hole was there in the "frame" cross member above the axle, so by buying a new spring plate with the stud for the lower end of the shock it was an easy conversion. The difference was incredible.
All of which is a long way of recommending a traction bar of some kind if you're going to set up both shocks on the same side of the axle.